Preheat grill to 400-475. Prepare oysters using an oyster knife and shucking severing the muscle that is attaching the oyster to the shell. Leave the oyster in the shell that is more cupped shaped.
In a saucepan, combine the butter, whiskey, brown sugar, garlic, and cayenne. Stir until well-mixed. Over a low flame heat until butter melts, whiskey cooks off, and sugar dissolves. Let cool and then place up to 1 tbsp (depending on oyster size) of the mixture on each oyster.
Place the oysters in a single layer on a grill. Grill uncovered for 6-7 minutes until the butter mixture is sizzling and the oyster is puffed up. Remove from the grill and serve immediately.
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